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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
If dilute acid is not used, the early precipitation of 4th group cations (if present in solution) may occur, thus leading to misleading results. Acids beside HCl are rarely used. Sulfuric acid may lead to the precipitation of the 5th group cations, whereas nitric acid oxidises the sulfide ion in the reagent, forming colloidal sulfur.
The reaction of calcium carbide with water, producing acetylene and calcium hydroxide, [5] was discovered by Friedrich Wöhler in 1862. CaC 2 + 2 H 2 O → C 2 H 2 + Ca(OH) 2 . This reaction was the basis of the industrial manufacture of acetylene, and is the major industrial use of calcium carbide.
Calcium oxalate is a combination of calcium ions and the conjugate base of oxalic acid, the oxalate anion. Its aqueous solutions are slightly basic because of the basicity of the oxalate ion. The basicity of calcium oxalate is weaker than that of sodium oxalate, due to its lower solubility in water.
Gravimetric analysis describes a set of methods used in analytical chemistry for the quantitative determination of an analyte (the ion being analyzed) based on its mass. The principle of this type of analysis is that once an ion's mass has been determined as a unique compound, that known measurement can then be used to determine the same analyte's mass in a mixture, as long as the relative ...
Calcium deposits, primarily composed of calcium carbonate (CaCO 3), react with weak acids to form calcium salts that are soluble in water. The general reaction can be represented as follows: CaCO 3 + 2H + → Ca 2+ + CO 2 + H 2 O. Here, H + represents the hydrogen ions provided by the acid.
The results obtained are in mol%, but the method has its place, where other methods of analysis fail. In the laboratory, lauric acid may be used to investigate the molar mass of an unknown substance via the freezing-point depression. The choice of lauric acid is convenient because the melting point of the pure compound is relatively high (43.8 ...