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Nitrogen fertilizers are made from ammonia (NH 3) produced by the Haber–Bosch process. [28] In this energy-intensive process, natural gas (CH 4) usually supplies the hydrogen, and the nitrogen (N 2) is derived from the air. This ammonia is used as a feedstock for all other nitrogen fertilizers, such as anhydrous ammonium nitrate (NH 4 NO 3 ...
When discussing the application of nitrogen in agriculture, it is essential to consider the sources of nitrogen used. Synthetic nitrogen fertilizers, such as ammonium nitrate and urea, are commonly applied to crops to replenish soil nitrogen levels and enhance crop productivity [3] These fertilizers provide readily available nitrogen for plant ...
Ammonia volatilization reduces the economic efficiency of agricultural cropping systems. Either yield will be reduced or additional costs will be incurred from additional nitrogen fertilizer. The amount of ammonia volatilization depends on several environmental factors, including temperature, pH, and the soil water content.
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
In the soil, the ammonium ion is released and forms a small amount of acid, lowering the pH balance of the soil, while contributing essential nitrogen for plant growth. One disadvantage to the use of ammonium sulfate is its low nitrogen content relative to ammonium nitrate, which elevates transportation costs. [2]
Ammonia is produced biologically in a process called nitrogen fixation, but even more is generated industrially by the Haber process. The process helped revolutionize agriculture by providing cheap fertilizers. The global industrial production of ammonia in 2021 was 235 million tonnes.