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Pyrrole is an extremely weak base for an amine, with a conjugate acid pK a of −3.8. The most thermodynamically stable pyrrolium cation (C 4 H 6 N +) is formed by protonation at the 2 position. Substitution of pyrrole with alkyl substituents provides a more basic molecule—for example, tetramethylpyrrole has a conjugate acid pK a of +3.7.
Porphyrazines, or tetraazaporphyrins, are tetrapyrrole macrocycles similar to porphyrins and phthalocyanines.Pioneered by Sir R. Patrick Linstead as an extension of his work on phthalocyanines, [1] porphyrazines differ from porphyrins in that they contain -meso nitrogen atoms, rather than carbon atoms, and differ from phthalocyanines in that their β-pyrrole positions are open for substitution.
Polypyrrole Pyrrole can be polymerised electrochemically. [1] Polypyrrole (PPy) is an organic polymer obtained by oxidative polymerization of pyrrole. It is a solid with the formula H(C 4 H 2 NH) n H. It is an intrinsically conducting polymer, used in electronics, optical, biological and medical fields. [2] [3]
In organic chemistry, the Paal–Knorr synthesis is a reaction used to synthesize substituted furans, pyrroles, or thiophenes from 1,4-diketones.It is a synthetically valuable method for obtaining substituted furans and pyrroles, which are common structural components of many natural products.
Only one regioisomer was observed. In this case, the reaction conditions were sufficient to form the N-vinyl pyrrole [4] 2-mesityl-3-methylpyrrole was synthesized in 2004 via the Trofimov reaction. The reaction of the ketoxime with acetylene yielded a mixture of products with the primary one being the N-H pyrrole.
2,2'-Dipyrromethene, often called just dipyrromethene or dipyrrin, is a chemical compound with formula C 9 H 8 N 2 whose skeleton can be described as two pyrrole rings C 5 N connected by a methyne bridge =CH– through their nitrogen-adjacent (position-2) carbons; the remaining bonds being satisfied by hydrogen atoms.
The pyrrole-like rings within H 2 Pc are closely related to isoindole. Both porphyrins and phthalocyanines function as planar tetradentate dianionic ligands that bind metals through four inwardly projecting nitrogen centers. Such complexes are formally derivatives of Pc 2−, the conjugate base of H 2 Pc.
The Bases Conversion and Development Authority (BCDA; Filipino: Pangasiwaan sa Pangkaunlarang Kumbersiyon ng mga Base [4]) is a government-owned and controlled corporation under the Office of the President of the Philippines.