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Biological substances can experience leaching themselves, [2] as well as be used for leaching as part of the solvent substance to recover heavy metals. [6] Many plants experience leaching of phenolics, carbohydrates, and amino acids, and can experience as much as 30% mass loss from leaching, [5] just from sources of water such as rain, dew, mist, and fog. [2]
The chelators bind the copper ions (and no other ions, ideally), the resulting complexes dissolve in the organic phase. This organic solvent is evaporated, leaving a residue of the copper complexes. The copper ions are liberated from the residue with sulfuric acid. The barred (denuded) sulfuric acid recycled back on to the heaps.
This method is an acid heap leaching method like that of the copper method in that it utilises sulfuric acid instead of cyanide solution to dissolve the target minerals from crushed ore. The amount of sulfuric acid required is much higher than for copper ores, as high as 1,000 kg of acid per tonne of ore, but 500 kg is more common.
There are four types of leaching: [not verified in body] Cyanide leaching (e.g. gold ore) Ammonia leaching (e.g. crushed ore) Alkali leaching (e.g. bauxite ore) Acid leaching (e.g. sulfide ore) [1] [2] Leaching is also notable in the extraction of rare earth elements, which consists of lanthanides, yttrium and scandium. [2]
In-situ leaching of copper was done by the Chinese by 907 AD, and perhaps as early as 177 BC. [4] Copper is usually leached using acid (sulfuric acid or hydrochloric acid), then recovered from solution by solvent extraction electrowinning (SX-EW) or by chemical precipitation.
Copper is precipitated as its sulfide as a means to purify nickel leachates. Cementation is the conversion of the metal ion to the metal by a redox reaction. A typical application involves addition of scrap iron to a solution of copper ions. Iron dissolves and copper metal is deposited. Solvent Extraction; Ion exchange; Gas reduction.
The beneficiation process for oxides involves extraction with sulfuric acid solutions followed by electrolysis. In parallel with the above method for "concentrated" sulfide and oxide ores, copper is recovered from mine tailings and heaps. A variety of methods are used including leaching with sulfuric acid, ammonia, ferric chloride.
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color . Copper also has a range of different organic and inorganic salts , having varying oxidation states ranging from (0,I) to (III).