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Fullerene or C 60 is soccer-ball-shaped or I h with 12 pentagons and 20 hexagons. According to Euler's theorem these 12 pentagons are required for closure of the carbon network consisting of n hexagons and C 60 is the first stable fullerene because it is the smallest possible to obey this rule.
In 2013 researchers discovered that asymmetrical fullerenes formed from larger structures settle into stable fullerenes. The synthesized substance was a particular metallofullerene consisting of 84 carbon atoms with two additional carbon atoms and two yttrium atoms inside the cage.
In organic chemistry, spherical aromaticity is formally used to describe an unusually stable nature of some spherical compounds such as fullerenes and polyhedral boranes. In 2000, Andreas Hirsch and coworkers in Erlangen , Germany , formulated a rule to determine when a spherical compound would be aromatic .
Besides unfilled fullerenes, endohedral metallofullerenes develop with different cage sizes like La@C 60 or La@C 82 and as different isomer cages. Aside from the dominant presence of mono-metal cages, numerous di-metal endohedral complexes and the tri-metal carbide fullerenes like Sc 3 C 2 @C 80 were also isolated. In 1999 a discovery drew ...
They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways. Fullerene-containing polymers are divided into following structural categories: Intrinsic polymeric fullerene (homopolymer), Main-chain polymers, Side-chain polymers, Star polymers, Crosslinked polymers,
Fullerenes are typically spheroidal carbon compounds, the most prevalent being buckminsterfullerene, C 60. [2] One year after it was prepared in milligram quantities in 1990, [3] C 60 was shown to function as a ligand in the complex [Ph 3 P] 2 Pt(η 2-C 60). [4] Since this report, a variety of transition metals and binding modes were demonstrated.
It’s been one year since three of Jordan Willis’ friends, Clayton McGeeney, David Harrington and Ricky Johnson, were found dead outside Willis’ rental home in Kansas City, Mo.
The regions with higher density of stars are shown; these correspond with known star clusters (Hyades and Coma Berenices) and moving groups. This is a list of nearby stellar associations and moving groups. A stellar association is a very loose star cluster, looser than an open cluster. A moving group is the remnant of such a stellar association ...