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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
In chemistry, the molar mass (M) (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical compound is defined as the ratio between the mass and the amount of substance (measured in moles) of any sample of the compound. [1] The molar mass is a bulk, not molecular, property of a substance.
DEHPA is prepared through the reaction of phosphorus pentoxide and 2-ethylhexanol: 4 C 8 H 17 OH + P 4 O 10 → 2 [(C 8 H 17 O)PO(OH)] 2 O [(C 8 H 17 O)PO(OH)] 2 O + C 8 H 17 OH → (C 8 H 17 O) 2 PO(OH) + (C 8 H 17 O)PO(OH) 2. These reaction produce a mixture of mono-, di-, and trisubstituted phosphates, from which DEHPA can be isolated based ...
Unprocessed phosphate rock has a concentration of 1.7–8.7% phosphorus by mass (4–20% phosphorus pentoxide). By comparison, the Earth's crust contains 0.1% phosphorus by mass, [84] and vegetation 0.03–0.2%. [85] Although quadrillions of tons of phosphorus exist in the Earth's crust, [86] these are currently not economically extractable.
Phosphorus oxide can refer to: Phosphorus pentoxide (phosphorus(V) oxide, phosphoric anhydride), P 2 O 5; Phosphorus trioxide (phosphorus(III) oxide, phosphorous anhydride), P 2 O 3; Phosphorus tetroxide, P 2 O 4; Several other, less common, oxides of phosphorus, including P 4 O 7, P 4 O 9, and P 2 O 6; Gases: Phosphorus monoxide, PO ...
Elemental phosphorus is distilled out of the furnace and burned with air to produce high-purity phosphorus pentoxide, which is dissolved in water to make phosphoric acid. [22] The thermal process produces phosphoric acid with a very high concentration of P 2 O 5 (about 85%) and a low level of impurities.
Ammonium difluorophosphate ([NH 4]PO 2 F 2) is formed from treating phosphorus pentoxide with ammonium fluoride. [2] This was how the ion was first made by its discoverer, Willy Lange, in 1929. [3] [5] Alkali metal chlorides can react with dry difluorophosphoric acid to form alkali metal salts. [6] NaCl + HPO 2 F 2 → NaPO 2 F 2 + HCl
Peroxyphosphoric acid is usually produced by treating phosphorus pentoxide and concentrated hydrogen peroxide within an inert solvent like acetonitrile or carbon tetrachloride. [3] [4] P 4 O 10 + 4 H 2 O 2 + 2 H 2 O → 4 H 3 PO 5. One method of preparation is the hydrolysis of potassium of lithium peroxydiphosphate in a strong acid such as ...