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2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (or DDQ) is the chemical reagent with formula C 6 Cl 2 (CN) 2 O 2. This oxidant is useful for the dehydrogenation of alcohols, [3] phenols, [4] and steroid ketones. [5] DDQ decomposes in water, but is stable in aqueous mineral acid. [6]
The use of protective groups is pervasive but not without criticism. [103] In practical terms their use adds two steps (protection-deprotection sequence) to a synthesis, either or both of which can dramatically lower chemical yield. Crucially, added complexity impedes the use of synthetic total synthesis in drug discovery.
p-Methoxybenzyl (PMB) is used as a protecting group for alcohols in organic synthesis (4-Methoxybenzylthiol is used to protect thiols). The p -methoxybenzyl group Strong base such as powdered potassium hydroxide or sodium hydride and p -methoxybenzyl halide (chloride or bromide) [ 14 ] [ 15 ]
Toad is a database management toolset from Quest Software for managing relational and non-relational databases using SQL aimed at database developers, database administrators, and data analysts. The Toad toolset runs against Oracle, SQL Server, IBM DB2 (LUW & z/OS), SAP and MySQL. A Toad product for data preparation supports many data platforms.
PMB was initially licensed under GNU General Public License, which ensures the free availability of the software. Wiki, mailing lists and BerliOS hosting facilities allow communication between PMB developers and users. PMB is now licensed under CECILL free licence, that ensures legal security in France and other countries with similar legal ...
The OS 2200 database managers are all part of the Universal Data System (UDS). UDS provides a common control structure for multiple different data models. Flat files (sequential, multi-keyed indexed sequential, MSAM, and fixed-block), [1] network, [2] and relational [3] data models all share a common locking, recovery, and clustering mechanism.
In SQL, the data manipulation language comprises the SQL-data change statements, [3] which modify stored data but not the schema or database objects. Manipulation of persistent database objects, e.g., tables or stored procedures, via the SQL schema statements, [3] rather than the data stored within them, is considered to be part of a separate data definition language (DDL).
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