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Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Sometimes an abbreviated form of the element name has to be taken, e.g. germide for germanium as germanide refers to GeH − 3. Polyatomic cations of the same element are named as the element name preceded by di-, tri-, etc., e.g.: Hg 2+ 2 dimercury(2+) Polyatomic cations made up of different elements are named either substitutively or ...
The nomenclature of the peroxy group is somewhat variable, [4] and exists as an exception to the rules of naming polyatomic ions. This is because, when it was discovered, it was believed to be monatomic. [ 5 ]
Some ionic compounds contain polyatomic ions, which are charged entities containing two or more covalently bonded types of atoms. It is important to know the names of common polyatomic ions; these include: ammonium (NH + 4) nitrite (NO − 2) nitrate (NO − 3) sulfite (SO 2− 3) sulfate (SO 2− 4) hydrogen sulfate (bisulfate) (HSO − 4 ...
Cations are positively (+) charged ions while anions are negatively (−) charged. This can be remembered with the help of the following mnemonics. Cats have paws ⇔ Cations are pawsitive. [23] Ca+ion: The letter t in cation looks like a + (plus) sign. [24] An anion is a negative ion. (An egative ion ⇒ Anion). [25]
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).