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  2. Electrochemical cell - Wikipedia

    en.wikipedia.org/wiki/Electrochemical_cell

    A galvanic cell (voltaic cell), named after Luigi Galvani (Alessandro Volta), is an electrochemical cell that generates electrical energy from spontaneous redox reactions. [3]

  3. List of unsolved problems in chemistry - Wikipedia

    en.wikipedia.org/wiki/List_of_unsolved_problems...

    [12] What is a reliable ... "First 25 of 125 big questions that face scientific inquiry over the next quarter-century". Science. 309 (125th Anniversary). 1 July 2005.

  4. Electrochemistry - Wikipedia

    en.wikipedia.org/wiki/Electrochemistry

    Electrochemistry also has important applications in the food industry, like the assessment of food/package interactions, [36] the analysis of milk composition, [37] the characterization and the determination of the freezing end-point of ice-cream mixes, or the determination of free acidity in olive oil.

  5. Reference electrode - Wikipedia

    en.wikipedia.org/wiki/Reference_electrode

    They are a class of electrodes named pseudo-reference electrodes because they do not maintain a constant potential but vary predictably with conditions. If the conditions are known, the potential can be calculated and the electrode can be used as a reference.

  6. Butler–Volmer equation - Wikipedia

    en.wikipedia.org/wiki/Butler–Volmer_equation

    The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium).

  7. Liquid junction potential - Wikipedia

    en.wikipedia.org/wiki/Liquid_junction_potential

    Liquid junction potential (shortly LJP) occurs when two solutions of electrolytes of different concentrations are in contact with each other. The more concentrated solution will have a tendency to diffuse into the comparatively less concentrated one.

  8. Half-cell - Wikipedia

    en.wikipedia.org/wiki/Half-cell

    In electrochemistry, a half-cell is a structure that contains a conductive electrode and a surrounding conductive electrolyte separated by a naturally occurring Helmholtz double layer. Chemical reactions within this layer momentarily pump electric charges between the electrode and the electrolyte, resulting in a potential difference between the ...

  9. Nernst equation - Wikipedia

    en.wikipedia.org/wiki/Nernst_equation

    In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...