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When 1-[14 C]-1-chlorobenzene was subjected to aqueous NaOH at 395 °C, ipso substitution product 1-[14 C]-phenol was formed in 54% yield, while cine substitution product 2-[14 C]-phenol was formed in 43% yield, indicating that an elimination-addition (benzyne) mechanism is predominant, with perhaps a small amount of product from addition ...
The Raschig–Hooker process suffers from selectivity issues in both steps. In the first step, the reaction is only run to 10% to 15% conversion to prevent the second addition of a chlorine atom to the desired chlorobenzene. Despite this, the overall selectivity of the reaction is 70% to 85%.
Phenol is a component in liquid–liquid phenol–chloroform extraction technique used in molecular biology for obtaining nucleic acids from tissues or cell culture samples. Depending on the pH of the solution either DNA or RNA can be extracted. Phenol is so inexpensive that it also attracts many small-scale uses.
Bis(phenol) substrates undergo oxidative coupling under these conditions. Iodonium ylides are relatively stable, versatile compounds that undergo substitution and cycloaddition reactions. They are represented using two resonance forms, one zwitterionic (the "betaine" form) and the other neutral (the "ylide" form).
In female elephants, the two compounds 3-ethyl phenol and 2-ethyl 4,5 dimethylphenol have been detected in urine samples. [70] Temporal glands secretion examination showed the presence of phenol, m-cresol and p-cresol (4-methyl phenol) during musth in male elephants. [71] [72] [73] p-Cresol and o-cresol are also components of the human sweat.
To calculate phenol coefficient, the concentration of phenol at which the compound kills the test organism in 10 minutes, but not in 5 minutes, is divided by the concentration of the test compound that kills the organism under the same conditions (or, probably more common, dividing the dilution factor at which the tested substance shows ...
Phenol is a polar substance with a higher density than water (1.07 g/cm 3 [2] compared to water's 1.00 g/cm 3). When suspended in a water-phenol solution, denatured proteins and unwanted cell components dissolve in the phenol, while polar nucleic acids dissolve in the water phase. [3]
At 1 ppm the solution is a very pale yellow. As the concentration increases the colour becomes a more vibrant yellow, then orange, with the final 10,000 ppm a deep red colour. In science and engineering , the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities , e.g. mole fraction or ...