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One liquid carried a positive charge, and the other a negative charge. When these two liquids came into contact with one another, they would produce a neutral charge. [3] This theory dealt mainly with explaining electrical attraction and repulsion, rather than how an object could be charged or discharged.
Electrons are affected by two thermodynamic forces [from the charge, ∇(E F /e c) where E F is the Fermi level and e c is the electron charge and temperature gradient, ∇(1/T)] because they carry both charge and thermal energy, and thus electric current j e and heat flow q are described with the thermoelectric tensors (A ee, A et, A te, and A ...
e is the electric charge of an electron; For a metal, described by a Fermi gas (Fermi liquid), quantum version of the Einstein relation should be used. Typically, temperature is much smaller than the Fermi energy, in this case one should use the following formula: = where:
"Energy current" is a somewhat informal term that is used, on occasion, to describe the process of energy transfer in situations where the transfer can usefully be viewed in terms of a flow. It is particularly used when the transfer of energy is more significant to the discussion than the process by which the energy is transferred.
Mass transfer in a system is governed by Fick's first law: 'Diffusion flux from higher concentration to lower concentration is proportional to the gradient of the concentration of the substance and the diffusivity of the substance in the medium.' Mass transfer can take place due to different driving forces. Some of them are: [12]
Electroosmotic flow is caused by the Coulomb force induced by an electric field on net mobile electric charge in a solution. Because the chemical equilibrium between a solid surface and an electrolyte solution typically leads to the interface acquiring a net fixed electrical charge, a layer of mobile ions, known as an electrical double layer or Debye layer, forms in the region near the interface.
The convection heat transfer mode comprises two mechanism. In addition to energy transfer due to specific molecular motion , energy is transferred by bulk, or macroscopic, motion of the fluid. This motion is associated with the fact that, at any instant, large numbers of molecules are moving collectively or as aggregates.
This will result in an electrical double layer of positive and negative charges at the junction of the two solutions. Thus at the point of junction, a potential difference will develop because of the ionic transfer. This potential is called liquid junction potential or diffusion potential which is non-equilibrium potential. The magnitude of the ...