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The phenomenon of freezing-point depression has many practical uses. The radiator fluid in an automobile is a mixture of water and ethylene glycol. The freezing-point depression prevents radiators from freezing in winter. Road salting takes advantage of this effect to lower the freezing point of the ice it is placed on.
The van 't Hoff factor i (named after Dutch chemist Jacobus Henricus van 't Hoff) is a measure of the effect of a solute on colligative properties such as osmotic pressure, relative lowering in vapor pressure, boiling-point elevation and freezing-point depression.
Supercooling is the cooling of a liquid below its freezing point without it becoming solid. Freezing point depression is when a solution can be cooled below the freezing point of the corresponding pure liquid due to the presence of the solute; an example of this is the freezing point depression that occurs when salt is added to pure water.
The term "cryoscopy" means "freezing measurement" in Greek. Freezing point depression is a colligative property, so ΔT depends only on the number of solute particles dissolved, not the nature of those particles. Cryoscopy is related to ebullioscopy, which determines the same value from the ebullioscopic constant (of boiling point elevation).
Freezing point depression and boiling point elevation In chemistry , colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. [ 1 ]
Freezing Point Depression and Related Phenomena". It was originally published in 1923 in volume 24 of a German-language journal Physikalische Zeitschrift . An English translation [ 21 ] : 217–63 of the article is included in a book of collected papers presented to Debye by "his pupils, friends, and the publishers on the occasion of his ...
The extent of freezing point depression observed in DESs is well illustrated by a mixture of choline chloride and urea in a 1:2 mole ratio. Choline chloride and urea are both solids at room temperature with melting points of 302 °C (decomposition point) and 133 °C respectively, yet the combination of the two in a 1:2 molar ratio forms a ...
In thermodynamics, the ebullioscopic constant K b relates molality b to boiling point elevation. [1] It is the ratio of the latter to the former: = i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution.