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Written as a reduction, cathodic current is positive. The net current density is the difference between the cathodic and anodic current density. Exchange current densities reflect intrinsic rates of electron transfer between an analyte and the electrode. Such rates provide insights into the structure and bonding in the analyte and the electrode.
In heterogeneous electron transfer, an electron moves between a chemical species present in solution and the surface of a solid such as a semi-conducting material or an electrode. Theories addressing heterogeneous electron transfer have applications in electrochemistry and the design of solar cells .
There are two rates which determine the current-voltage relationship for an electrode. First is the rate of the chemical reaction at the electrode, which consumes reactants and produces products. This is known as the charge transfer rate. The second is the rate at which reactants are provided, and products removed, from the electrode region by ...
The exchange current is the current at equilibrium, i.e. the rate at which oxidized and reduced species transfer electrons with the electrode. In other words, the exchange current density is the rate of reaction at the reversible potential (when the overpotential is zero by definition).
The Faradaic current - which is due to electron transfer events and is most often the current component of interest - decays as described in the Cottrell equation. In most electrochemical cells, this decay is much slower than the charging decay-cells with no supporting electrolyte are notable exceptions.
In other media, any stream of charged objects (ions, for example) may constitute an electric current. To provide a definition of current independent of the type of charge carriers, conventional current is defined as moving in the same direction as the positive charge flow. So, in metals where the charge carriers (electrons) are negative ...
Diffusion current is a current in a semiconductor caused by the diffusion of charge carriers (electrons and/or electron holes). This is the current which is due to the transport of charges occurring because of non-uniform concentration of charged particles in a semiconductor.
Because exchange of W bosons involves a transfer of electric charge (as well as a transfer of weak isospin, while weak hypercharge is not transferred), it is known as "charged current". By contrast, exchanges of Z bosons involve no transfer of electrical charge, so it is referred to as a "neutral current". In the latter case, the word "current ...