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Oxidation of pyrite in clay formations in contact with concrete – this produces sulfuric acid which reacts with concrete. Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S).
Example of flat piece of concrete having dislodged with corroded rebar underneath, Welland River bridge across Queen Elizabeth Way in Niagara Falls, Ontario. The expansion of the corrosion products (iron oxides) of carbon steel reinforcement structures may induce internal mechanical stress (tensile stress) that cause the formation of cracks and disrupt the concrete structure.
The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. The effect of sulfuric acid on concrete and steel surfaces exposed to severe wastewater environments can be devastating. [1] In the USA alone, corrosion causes sewer asset losses estimated at $14 billion per year. [2]
Iron(II) sulfide or ferrous sulfide (Br.E. sulphide) is one of a family of chemical compounds and minerals with the approximate formula Fe S. Iron sulfides are often ...
Samples of "ground granulated blast furnace slag" (left) and "granulated blast furnace slag" (right) Ground granulated blast-furnace slag (GGBS or GGBFS) is obtained by quenching molten iron slag (a by-product of iron and steel-making) from a blast furnace in water or steam, to produce a glassy, granular product that is then dried and ground into a fine powder.
Iron minerals can active for dechlorination. These minerals use Fe 2+. Particular minerals that can be used include green rust, magnetite, pyrite, and glauconite. [6] The most reactive of the iron minerals are the iron sulfides and oxides. Pyrite, an iron sulfide, is able to dechlorinate carbon tetrachloride in suspension. [2]
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