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Selenium tetrafluoride (Se F 4) is an inorganic compound.It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
trineodymium fluoride tetraselenite Nd 3 (SeO 3) 4 F hexagonal P6 3 mc: a=10.515 c=7.1211 [23] trisamarium fluoride tetraselenite Sm 3 (SeO 3) 4 F hexagonal P6 3 mc: a=10.474 c=7.0224 [23] trigadolinium tetraselenite fluoride Gd 3 (SeO 3) 4 F 4:1 hexagonal P6 3 mc: a = 10.443 b = 6.9432 Z=2 [24] [1] tridysprosium tetraselenite fluoride Dy 3 ...
Pentafluoroselenium hypofluorite can also formed from selenium oxyfluoride and fluorine gas in the presence of potassium fluoride. [4] [5] SeOF 2 + KF → K + [SeOF 3] − — F 2 → K + [SeOF 5] − — F 2 → KF + SeOF 6. The reaction of fluorine gas and Hg(OSeF 5) 2 produces SeOF 6 in much higher yield and with less SeF 6. [3]
Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
Selenoyl fluoride can be formed by the action of warm fluorosulfonic acid on barium selenate [5] or selenic acid. SeO 3 + SeF 4 can give this gas along with other oxyfluorides. Reactions
Seleninyl fluoride can be produced by the reaction of selenium oxychloride and potassium fluoride. [3] 2 KF + SeOCl 2 → 2 KCl + SeOF 2. It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide. [2] SeF 4 + H 2 O → SeOF 2 + 2 HF SeF 4 + SeO 2 → 2 SeOF 2
Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states , the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite , guanajuatite , tiemannite , crookesite etc., and can also coexist with ...