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Fluorine substitution, usually of a single atom or at most a trifluoromethyl group, is a robust modification with effects analogous to fluorinated pharmaceuticals: increased biological stay time, membrane crossing, and altering of molecular recognition. [210]
Fluorine's chemistry is dominated by its strong tendency to gain an electron. It is the most electronegative element and elemental fluorine is a strong oxidant. The removal of an electron from a fluorine atom requires so much energy that no known reagents are known to oxidize fluorine to any positive oxidation state. [20]
Fluorine, in the form of fluoride, is considered to be a micronutrient for human health, necessary to prevent dental cavities, and to promote healthy bone growth. [28] The tea plant (Camellia sinensis L.) is a known accumulator of fluorine compounds, released upon forming infusions such as the common beverage. The fluorine compounds decompose ...
Fluorine (9 F) has 19 known isotopes ranging from 13 F to 31 F and two isomers (18m F and 26m F). Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element. The longest-lived radioisotope is 18 F; it has a half-life of 109.734(8) min. All other fluorine ...
And any created fluorine within stars is rapidly eliminated through strong nuclear fusion reactions—either with hydrogen to form oxygen and helium, or with helium to make neon and hydrogen. [ 2 ] [ 3 ] The presence of fluorine at all—outside of temporary existence in stars—is somewhat of a mystery because of the need to escape these ...
1,1,1,2-tetrafluorodisulfane, also known as 1,2-difluorodisulfane 1,1-difluoride or just difluorodisulfanedifluoride (FSSF 3) is an unstable molecular compound of fluorine and sulfur. The molecule has a pair of sulfur atoms, with one fluorine atom on one sulfur, and three fluorine atoms on the other.
Fluorine-19 nuclear magnetic resonance spectroscopy (fluorine NMR or 19 F NMR) is an analytical technique used to detect and identify fluorine-containing compounds. 19 F is an important nucleus for NMR spectroscopy because of its receptivity and large chemical shift dispersion, which is greater than that for proton nuclear magnetic resonance ...
Fluorine-18 (18 F, also called radiofluorine) is a fluorine radioisotope which is an important source of positrons. It has a mass of 18.0009380(6) u and its half-life is 109.771(20) minutes. It decays by positron emission 96.7% of the time and electron capture 3.3% of the time.