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The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
It handles instantaneous, continuous, and pool releases, and can model gases, particulates, and liquids. The model has a three regime structure: that of single building (area density < 5%), urban array (area density > 5%) and open. The model can be coupled with the US model SCIPUFF to replace the open regime and extend the model's prediction range.
The hard sphere system exhibits a fluid-solid phase transition between the volume fractions of freezing and melting . The pressure diverges at random close packing η r c p ≈ 0.644 {\displaystyle \eta _{\mathrm {rcp} }\approx 0.644} for the metastable liquid branch and at close packing η c p = 2 π / 6 ≈ 0.74048 {\displaystyle \eta ...
The non-random two-liquid model [1] (abbreviated NRTL model) is an activity coefficient model introduced by Renon and Prausnitz in 1968 that correlates the activity coefficients of a compound with its mole fractions in the liquid phase concerned. It is frequently applied in the field of chemical engineering to calculate phase equilibria.
The fugacity of a condensed phase (liquid or solid) is defined the same way as for a gas: = and = It is difficult to measure fugacity in a condensed phase directly; but if the condensed phase is saturated (in equilibrium with the vapor phase), the chemical potentials of the two phases are equal (μ c = μ g).
The starting point for a mathematical description of almost any type of fluid flow is the classical set of Navier–Stokes equations.To describe particle-laden flows, we must modify these equations to account for the effect of the particles on the carrier, or vice versa, or both - a suitable choice of such added complications depend on a variety of the parameters, for instance, how dense the ...
The UNIQUAC model can be considered a second generation activity coefficient because its expression for the excess Gibbs energy consists of an entropy term in addition to an enthalpy term. Earlier activity coefficient models such as the Wilson equation and the non-random two-liquid model (NRTL model) only consist of enthalpy terms.
A similar concept applies to liquid–gas phase changes. [7] Water is an exception which has a solid-liquid boundary with negative slope so that the melting point decreases with pressure. This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water.