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The Dumas method of molecular weight determination was historically a procedure used to determine the molecular weight of an unknown volatile substance. [ 1 ] [ 2 ] The method was designed by the French chemist Jean Baptiste André Dumas , after whom the procedure is now named.
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
If the relationship between the molar mass and Vh of the standard is not the same as that of the unknown sample, then the calibration is invalid. Thus, to be accurate, the calibration must use the same polymer, of the same conformation, in the same eluent and have the same interaction with the solvent as the hydration layer changes Vh.
M 2 is the molar mass of gas 2. Graham's law states that the rate of diffusion or of effusion of a gas is inversely proportional to the square root of its molecular weight. Thus, if the molecular weight of one gas is four times that of another, it would diffuse through a porous plug or escape through a small pinhole in a vessel at half the rate ...
Atomic number Element Molar mass Formal standard atomic weight s.a.w., formal short Note Z calculated; g·mol −1 A r, standard [2] A r, abridged and conventional [2]; C 9 H 8 O 4: 180.159 g·mol −1
Equivalent weights may be calculated from molar masses if the chemistry of the substance is well known: sulfuric acid has a molar mass of 98.078(5) g mol −1, and supplies two moles of hydrogen ions per mole of sulfuric acid, so its equivalent weight is 98.078(5) g mol −1 /2 eq mol −1 = 49.039(3) g eq −1.
molar mass of carbon-12: ... and is strongly dependent on how those units are defined. For example, the atomic mass constant is exactly known when ...
The molecular mass and relative molecular mass are distinct from but related to the molar mass. The molar mass is defined as the mass of a given substance divided by the amount of the substance, and is expressed in grams per mol (g/mol). That makes the molar mass an average of many particles or molecules (potentially containing different ...