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Curing a thermosetting resin transforms it into a plastic, or elastomer by crosslinking or chain extension through the formation of covalent bonds between individual chains of the polymer. Crosslink density varies depending on the monomer or prepolymer mix, and the mechanism of crosslinking:
Phenolic resins, originally developed in the late 19th century and, regarded as the first truly synthetic polymer types, are often referred to as the “work-horse of thermosetting resins”. They are characterised by high bonding strength, dimensional stability and creep resistance at elevated temperatures, and frequently combined with co ...
Urea-formaldehyde (UF), also known as urea-methanal, so named for its common synthesis pathway and overall structure, [1] is a nontransparent thermosetting resin or polymer. It is produced from urea and formaldehyde. These resins are used in adhesives, plywood, particle board, medium-density fibreboard (MDF), and molded objects.
The function of the matrix in PMCs is to bond the fibers together and transfer loads between them. [2] PMCs matrices are typically either thermosets or thermoplastics. Thermosets are by far the predominant type in use today. Thermosets are subdivided into several resin systems including epoxies, phenolics, polyurethanes, and polyimides.
The chemistry of the cure reaction is a trimerization of three CN groups to a triazine ring. When the monomer contains two cyanate groups the resulting structure is a 3D polymer network . Thermoset polymer matrix properties can be fine tuned by the choice of substituents in the bisphenolic compound.
An acrylic resin is a thermoplastic or thermosetting plastic substance typically derived from acrylic acid, methacrylic acid and acrylate monomers such as butyl acrylate and methacrylate monomers such as methyl methacrylate. Thermoplastic acrylics designate a group of acrylic resins typically containing both a high molecular weight and a high ...
Polyester resins are thermosetting and, as with other resins, cure exothermically. The use of excessive initiator especially with a catalyst present can, therefore, cause charring or even ignition during the curing process. Excessive catalyst may also cause the product to fracture or form a rubbery material.
Polyamide-imide resin is hygroscopic, and picks up ambient moisture. Before processing the resin, drying is required to avoid brittle parts, foaming, and other molding problems. The resin must be dried to a moisture content of 500 ppm or less. A desiccant dryer capable of maintaining a dew point of −40 °F (−40 °C) is recommended. If ...
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