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The Wilke mixing rule is capable of describing the correct viscosity behavior of gas mixtures showing a nonlinear and non-monotonical behavior, or showing a characteristic bump shape, when the viscosity is plotted versus mass density at critical temperature, for mixtures containing molecules of very different sizes.
Index k = 2, because 3 is placed at an index that satisfies condition of being the largest index that is still less than a[k + 1] which is 4. Index l = 3, because 4 is the only value in the sequence that is greater than 3 in order to satisfy the condition a[k] < a[l]. The values of a[2] and a[3] are swapped to form the new sequence [1, 2, 4, 3].