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where ρ is the density of the substance under the applicable conditions. The corresponding expression for the ratio of specific heat capacities remains the same since the thermodynamic system size-dependent quantities, whether on a per mass or per mole basis, cancel out in the ratio because specific heat capacities are intensive properties. Thus:
The term specific heat may also refer to the ratio between the specific heat capacities of a substance at a given temperature and of a reference substance at a reference temperature, such as water at 15 °C; [5] much in the fashion of specific gravity. Specific heat capacity is also related to other intensive measures of heat capacity with ...
The volumetric heat capacity can also be expressed as the specific heat capacity (heat capacity per unit of mass, in J⋅K −1 ⋅kg −1) times the density of the substance (in kg/L, or g/mL). [1] It is defined to serve as an intensive property .
The heat capacity can usually be measured by the method implied by its definition: start with the object at a known uniform temperature, add a known amount of heat energy to it, wait for its temperature to become uniform, and measure the change in its temperature.
Thus, the ratio of the two values, γ, decreases with increasing temperature. However, when the gas density is sufficiently high and intermolecular forces are important, thermodynamic expressions may sometimes be used to accurately describe the relationship between the two heat capacities, as explained below.
The temperature of a system in thermal equilibrium is the same as the temperature of any part of it, so temperature is an intensive quantity. If the system is divided by a wall that is permeable to heat or to matter, the temperature of each subsystem is identical. Additionally, the boiling temperature of a substance is an intensive property.
The contribution of the muscle to the specific heat of the body is approximately 47%, and the contribution of the fat and skin is approximately 24%. The specific heat of tissues range from ~0.7 kJ · kg−1 · °C−1 for tooth (enamel) to 4.2 kJ · kg−1 · °C−1 for eye (sclera). [13]
Here, U is internal energy, T is absolute temperature, S is entropy, P is pressure, and V is volume. This is only one expression of the fundamental thermodynamic relation. It may be expressed in other ways, using different variables (e.g. using thermodynamic potentials). For example, the fundamental relation may be expressed in terms of the ...