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More formally, proposition B is a corollary of proposition A, if B can be readily deduced from A or is self-evident from its proof. In many cases, a corollary corresponds to a special case of a larger theorem, [4] which makes the theorem easier to use and apply, [5] even though its importance is generally considered to be secondary to that of ...
A common corollary of the statement is that heat does not spontaneously pass from a colder body to a warmer body. The third law of thermodynamics states that a system's entropy approaches a constant value as the temperature approaches absolute zero .
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
The Pythagorean theorem has at least 370 known proofs. [1]In mathematics and formal logic, a theorem is a statement that has been proven, or can be proven. [a] [2] [3] The proof of a theorem is a logical argument that uses the inference rules of a deductive system to establish that the theorem is a logical consequence of the axioms and previously proved theorems.
This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be calculated from tabulated enthalpies of formation and standard molar entropies of reactants and products. [19] [15] The chemical equilibrium condition at constant T and p without electrical work is dG = 0.
A representation of Hess's law (where H represents enthalpy) Hess's law of constant heat summation, also known simply as Hess's law, is a relationship in physical chemistry and thermodynamics [1] named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.
A porism is a mathematical proposition or corollary. It has been used to refer to a direct consequence of a proof, analogous to how a corollary refers to a direct consequence of a theorem. In modern usage, it is a relationship that holds for an infinite range of values but only if a certain condition is assumed, such as Steiner's porism. [1]
Jacobus van 't Hoff (1852–1911), an influential theoretical chemist and the first winner of the Nobel Prize in Chemistry.. Theoretical chemistry is the branch of chemistry which develops theoretical generalizations that are part of the theoretical arsenal of modern chemistry: for example, the concepts of chemical bonding, chemical reaction, valence, the surface of potential energy, molecular ...