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Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic , and inorganic chemistry.
With alkali metals, naphthalene forms the dark blue-green radical anion salts such as sodium naphthalene, Na + C 10 H − 8. The naphthalene anions are strong reducing agents. Naphthalene can be hydrogenated under high pressure in the presence of metal catalysts to give 1,2,3,4-tetrahydronaphthalene(C 10 H 12), also known as tetralin.
Naphthalenesulfonates are derivatives of sulfonic acid which contain a naphthalene functional unit. A related family of compounds are the aminonaphthalenesulfonic acids.Of commercial importance are the alkylnaphthalene sulfonates, which are used as superplasticizers in concrete.
Initiation of styrene polymerization with sodium naphthalene proceeds by electron transfer from the naphthalene radical anion to the monomer. The resulting radical dimerizes to give a disodium compound, which then functions as the initiator.
Poly-Etch is a sodium naphthalene complex in tetraglyme, [3] while Fluoro-Etch is a sodium naphthalide complex in diglyme [4] Matheson, the manufacturer of Poly-Etch, also manufactures a monoglyme-based etchant called Poly-Etch W. [5] Fulcrum Chemicals manufactures three different etchants called Natrex25, NatrexHighFp and Natrex64.
Naphthalene-2-sulfonic acid undergoes many reactions, some of which are or were of commercial interest. Fusion with sodium hydroxide followed by acidification gives 2-naphthol. It is an intermediate in the formation of 2,6-, 2,7- and 1,6-naphthalene disulfonic acids as well as 1,3,6-naphthalenetrisulfonic acid.
With solutions of naphthalene, it forms the deeply coloured radical sodium naphthalene, which is used as a soluble reducing agent: C 10 H 8 + Na → Na + [C 10 H 8] −• Structural studies show however that sodium naphthalene has no Na-C bond, the sodium is invariably coordinated by ether or amine ligands. [10]
It is added to help induce root formation in various plant types. It can also be applied by spraying it onto plants and which is typical in agricultural use. It is prohibited in many areas to use it in high concentrations due to the health concerns towards humans and other animals. NAA can be detected by HPLC-tandem mass spectrometry (HPLC-MS ...