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The above mechanism considered crystallization from the melt, which is important for injection molding of plastic components. Another type of crystallization occurs upon extrusion used in making fibers and films. In this process, the polymer is forced through, e.g., a nozzle that creates tensile stress which partially aligns its molecules. Such ...
Crystallization is the process by which solids form, where the atoms or molecules are highly organized into a structure known as a crystal.Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposition directly from a gas.
This process of draining helps to separate the pure crystals from the impure liquid. Sweating: This phase is a controlled partial melting process. It further purifies the product by melting only a small portion of the crystal. The melting causes the impurities trapped within or between the crystal structures to be released and separated.
The Lindemann criterion states that melting occurs because of "vibrational instability", e.g. crystals melt; when the average amplitude of thermal vibrations of atoms is relatively high compared with interatomic distances, e.g. <δu 2 > 1/2 > δ L R s, where δu is the atomic displacement, the Lindemann parameter δ L ≈ 0.20...0.25 and R s is ...
Crystallization; Crystal growth; Recrystallization; Seed crystal ... Recrystallization temperature is typically 0.3–0.4 times the melting point for pure metals and ...
This is known as the crystallization temperature (T c). This transition from amorphous solid to crystalline solid is an exothermic process, and results in a peak in the DSC signal. As the temperature increases the sample eventually reaches its melting temperature (T m). The melting process results in an endothermic peak in the DSC curve.
During the process of fractional crystallization, melts become enriched in incompatible elements. [14] Hence, knowledge of the crystallization sequence is critical in understanding how melt compositions evolve. Textures of rocks provide insights, as documented in the early 1900s by Bowen's reaction series. [15]
The flux method is a crystal growth method where starting materials are dissolved in a solvent (flux), and are precipitated out to form crystals of a desired compound. The flux lowers the melting point of the desired compound, analogous to a wet chemistry recrystallization. [1]