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Sodium polyacrylate (ACR, ASAP, or PAAS), [1]: 233 also known as waterlock, is a sodium salt of polyacrylic acid with the chemical formula [−CH 2 −CH(CO 2 Na)−] n and has broad applications in consumer products.
A SAP's ability to absorb water depends on the ionic concentration of the aqueous solution. In deionized and distilled water, a SAP may absorb 300 times its weight [4] (from 30 to 60 times its own volume) and can become up to 99.9% liquid, and when put into a 0.9% saline solution the absorbency drops to approximately 50 times its weight.
Polyacrylic acid is a weak anionic polyelectrolyte, whose degree of ionisation is dependent on solution pH. In its non-ionised form at low pHs, PAA may associate with various non-ionic polymers (such as polyethylene oxide, poly-N-vinyl pyrrolidone, polyacrylamide, and some cellulose ethers) and form hydrogen-bonded interpolymer complexes. [17]
Structure of a polyacrylate polymer. An acrylate polymer (also known as acrylic or polyacrylate) is any of a group of polymers prepared from acrylate monomers. These plastics are noted for their transparency, resistance to breakage, and elasticity. Acrylate polymer is commonly used in cosmetics, such as nail polish, as an adhesive. [1]
PSS is a 'strong' polyelectrolyte (fully charged in solution), whereas PAA is 'weak' (partially charged). Polyelectrolytes are polymers whose repeating units bear an electrolyte group. Polycations and polyanions are polyelectrolytes. These groups dissociate in aqueous solutions (water), making the polymers charged.
Isomers of the repeating unit in polyaspartic acid.. Polycarboxylates are used as builders in detergents. [2] Their high chelating power, even at low concentrations, reduces deposits on the laundry and inhibits the crystal growth of calcite.
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid.The acrylate ion is the anion CH 2 =CHCO − 2.Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate.
Hydrated water gel, or water beads. Water crystal gel or water beads or gel beads is any gel which absorbs and contains a large amount of water.Water gel is usually in spherical form and composed of a water-absorbing superabsorbent polymer (SAP, also known as slush powder in dry form) such as a polyacrylamide (frequently sodium polyacrylate).