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The twin thickness saturated once a critical residual dislocations’ density reached the coherent twin-parent crystal boundary. [ 33 ] [ 49 ] Significant attention has been paid to the crystallography , [ 50 ] morphology [ 51 ] and macro mechanical effects [ 52 ] of deformation twinning.
A twin boundary is a defect that introduces a plane of mirror symmetry in the ordering of a crystal. For example, in cubic close-packed crystals, the stacking sequence of a twin boundary would be ABCABCBACBA. On planes of single crystals, steps between atomically flat terraces can also be regarded as planar defects.
Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. Most grain boundaries are preferred sites for the onset of corrosion [1] and for the precipitation of new phases from the solid. They are also important to many of the mechanisms of creep. [2]
The approach to model these is similar to the Winterbottom construction, now adding an extra facet of energy per unit area half that of the twin boundary -- half so the energy per unit area of the two adjacent segments sums to a full twin boundary energy, and the facets that for the twin boundary are identical for thee segments.
On either side of this domain, the lattice is still perfect, and the boundaries of the domain are referred to as antiphase boundaries. [1] Crucially, crystals on either side of an antiphase boundary are related by a translation, rather than a reflection (a crystal twin ) or an inversion (an inversion domain ).
As the partial dislocations repel, stacking fault is created in between. By nature of stacking fault being a defect, it has higher energy than that of a perfect crystal, so acts to attract the partial dislocations together again. When this attractive force balance the repulsive force described above, the defects are in equilibrium state. [4]
Later Laurence D. Marks proposed a model using both experimental data and a theoretical analysis, which is based upon a modified Wulff construction which includes more surface facets, including Ino's {100} as well as re-entrant {111} surfaces at the twin boundaries with the possibility of others such as {110}, while retaining the decahedral ...
The existence of a topological defect can be demonstrated whenever the boundary conditions entail the existence of homotopically distinct solutions. Typically, this occurs because the boundary on which the conditions are specified has a non-trivial homotopy group which is preserved in differential equations; the solutions to the differential equations are then topologically distinct, and are ...