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Nevertheless, Lewis suggested that an electron-pair donor be classified as a base and an electron-pair acceptor be classified as acid. A more modern definition of a Lewis acid is an atomic or molecular species with a localized empty atomic or molecular orbital of low energy.
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...
The electron donating power of a donor molecule is measured by its ionization potential, which is the energy required to remove an electron from the highest occupied molecular orbital . The overall energy balance (ΔE), i.e., energy gained or lost, in an electron donor-acceptor transfer is determined by the difference between the acceptor's ...
The more stable electronic state is 2 B 1, where the unpaired electron is in the p-orbital perpendicular to the plane of the molecule (π type radical). The high energy electronic state, 2 A 1, has the two electrons in the p-orbital and the unpaired electron in the sp 2 orbital (σ type radical). [4] [5]
Amine. In chemistry, amines (/ ə ˈ m iː n, ˈ æ m iː n /, [1] [2] UK also / ˈ eɪ m iː n / [3]) are compounds and functional groups that contain a basic nitrogen atom with a lone pair.Formally, amines are derivatives of ammonia (NH 3 (in which the bond angle between the nitrogen and hydrogen is 107°), wherein one or more hydrogen atoms have been replaced by a substituent such as an ...
The Lewis theory is based on electronic structure. A Lewis base is a compound that can give an electron pair to a Lewis acid, a compound that can accept an electron pair. [14] [15] Lewis's proposal explains the Brønsted–Lowry classification using electronic structure. + + +
The electron accepting power of an electron acceptor is measured by its redox potential. [2] In the simplest case, electron acceptors are reduced by one electron. The process can alter the structure of the acceptor substantially. When the added electron is highly delocalized, the structural consequences of the reduction can be subtle.
In theoretical chemistry, Marcus theory is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called the electron acceptor). [1]