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[18] [19] This led to the discovery by Yasumitsu Aoki (Nemoto & Co.) of materials with luminance approximately 10 times greater than zinc sulfide and phosphorescence approximately 10 times longer. [20] [21] This has relegated most zinc sulfide based products to the novelty category. Strontium aluminate based pigments are now used in exit signs ...
An alternative to free-energy perturbation for computing potentials of mean force in chemical space is thermodynamic integration. Another alternative, which is probably more efficient, is the Bennett acceptance ratio method. Adaptations to FEP exist which attempt to apportion free-energy changes to subsections of the chemical structure. [5]
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite . Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment.
Silver, added to zinc sulfide to produce a phosphor/scintillator used in radium dials, spinthariscopes, and as a common blue phosphor in color CRTs, and to zinc sulfide-cadmium sulfide used as a phosphor in black-and-white CRTs (where the ZnS/(Zn,Cd)S ratio determines the blue/yellow balance of the resulting white); short afterglow
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
The red phosphor saw the most changes; it was originally manganese-activated zinc phosphate, then a silver-activated cadmium-zinc sulfide, then the europium(III) activated phosphors appeared; first in an yttrium vanadate matrix, then in yttrium oxide and currently in yttrium oxysulfide. The evolution of the phosphors was therefore (ordered by B ...
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
Ellingham diagrams are a particular graphical form of the principle that the thermodynamic feasibility of a reaction depends on the sign of ΔG, the Gibbs free energy change, which is equal to ΔH − TΔS, where ΔH is the enthalpy change and ΔS is the entropy change.