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Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) 'other' and τρόπος (tropos) 'manner, form') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
Carbon is capable of forming many allotropes (structurally different forms of the same element) due to its valency (tetravalent). Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched, including ball shapes such as buckminsterfullerene and sheets such as graphene.
Although white phosphorus forms the tetrahedron, the simplest possible Platonic hydrocarbon, no other polyhedral phosphorus clusters are known. [7] White phosphorus converts to the thermodynamically-stabler red allotrope, but that allotrope is not isolated polyhedra.
Although both are called "white phosphorus", in fact two different crystal allotropes are known, interchanging reversibly at 195.2 K. [5] The element's standard state is the body-centered cubic α form, which is actually metastable under standard conditions. [4] The β form is believed to have a hexagonal crystal structure. [5]
There are several known allotropes of oxygen. The most familiar is molecular oxygen (O 2), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (O 3). Others are: Atomic oxygen (O 1), a free radical. Singlet oxygen (O * 2), one of two metastable states of ...
[5] [6] The discovery of fullerenes greatly expanded the number of known allotropes of carbon, which had previously been limited to graphite, diamond, and amorphous carbon such as soot and charcoal. They have been the subject of intense research, both for their chemistry and for their technological applications, especially in materials science ...
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Graphene (/ ˈ ɡ r æ f iː n /) [1] is a carbon allotrope consisting of a single layer of atoms arranged in a honeycomb planar nanostructure. [2] [3] The name "graphene" is derived from "graphite" and the suffix -ene, indicating the presence of double bonds within the carbon structure.