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An example with modified reagents (sulfur, concentrated ammonium hydroxide and pyridine) is the conversion of acetophenone to 2-phenylacetamide and phenylacetic acid [5] The Willgerodt rearrangement using acetophenone
Factorio is a construction and management simulation game developed and published by Czech studio Wube Software. The game was announced via an Indiegogo crowdfunding campaign in 2013 and released for Windows , macOS , and Linux on 14 August 2020 following an early access phase, which was made available on 25 February 2016.
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Sulfation is a process used to remove "sulfur" from the combustion of fossil fuels. The goal is to minimize the pollution by the combusted gases. Combustion of sulfur-containing fuels releases sulfur dioxide , which, in the atmosphere, oxidizes to the equivalent of sulfuric acid , which is corrosive.
Atom Y may be sulfur, selenium, or nitrogen. If Y is nitrogen, the reaction is referred to as the Sommelet–Hauser rearrangement if a quaternary ammonium salt is involved or the aza-Wittig reaction if an alpha-metalated tertiary amine is involved; if Y is oxygen, then it is called a 2,3-Wittig rearrangement (not to be confused with the well ...
X is sulfur or rarely selenium and/or tellurium. [1] The Strunz classification includes the sulfosalts in a sulfides and sulfosalts superclass. [1] A group which have similar appearing formulas are the sulfarsenides (for example cobaltite (Co,Fe)AsS).
Sulfur polycations, S 8 2+, S 4 2+ and S 16 2+ are produced when sulfur is reacted with oxidising agents in a strongly acidic solution. [1] The colored solutions produced by dissolving sulfur in oleum were first reported as early as 1804 by C.F. Bucholz, but the cause of the color and the structure of the polycations involved was only ...
Reactions of sulfur ylides with ketones and aldehydes to form epoxides are by far the most common application of the Johnson–Corey–Chaykovsky reaction. Examples involving complex substrates and 'exotic' ylides have been reported, as shown below. [10] [11] Example 1 of epoxidation with CCR Example 1 of epoxidation with CCR