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4-Methylcyclohexene is an organic compound consisting of cyclohexene with a methyl group substituent attached to carbon most distant from the alkene group. Two other structural isomers are known: 1-methylcyclohexene and 3-methylcyclohexene .
It has been patented for use in air fresheners. [8]U.S. Patent 4915825 describes a froth flotation process for cleaning coal where a mixture of 95% MCHM, 4% water, and 0.1% 4-methylcyclohexanemethanol monoether (such as 4-(methoxymethyl)cyclohexanemethanol) is used as a frothing agent, and finely divided coal particles adhere to air bubbles induced into the agent which rise to the surface.
Most methylcyclohexane is extracted from petroleum but it can be also produced by catalytic hydrogenation of toluene: CH 3 C 6 H 5 + 3 H 2 → CH 3 C 6 H 11. The hydrocarbon is a minor component of automobile fuel, with its share in US gasoline varying between 0.3 and 1.7% in early 1990s [10] and 0.1 to 1% in 2011. [11]
Professor David Todd at Pomona College was testing the dehydration of 2-methylcyclohexanol or 4-methylcyclohexanol c. 1994 and unexpectedly interrupted the alkene distillation midway to have lunch with his secretary, Evelyn Jacoby. After lunch, he continued his distillation but kept the early products separate from the completed ones.
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Methylcyclohexanones are a group of three isomers: 2-methylcyclohexanone, 3-methylcyclohexanone, and 4-methylcyclohexanone. [1] They can be viewed as derivative of cyclohexanone. They can be prepared by oxidation of methylcyclohexane as well as partial hydrogenation of the corresponding cresols. All are colorless liquids.
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Download as PDF; Printable version ... a side product of the dehydration of 2-methylcyclohexanol into 1 ... Creative Commons Attribution-ShareAlike 4.0 ...