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Large amounts of sodium hypochlorite are also produced electrochemically via an un-separated chloralkali process. In this process brine is electrolyzed to form Cl 2 which dissociates in water to form hypochlorite. This reaction must be conducted in non-acidic conditions to prevent release of chlorine: 2 Cl − → Cl 2 + 2 e − Cl 2 + H 2 O ...
Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. [7]
The first solvation shell of a sodium ion dissolved in water. An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl ...
The reaction is driven by the low solubility of potassium chlorate in water. The equilibrium of the reaction is shifted to the right hand side by the continuous precipitation of the product (Le Chatelier's Principle). The precursor sodium chlorate is produced industrially in very large quantities by electrolysis of sodium chloride, common table ...
Potassium hypochlorite is produced by the disproportionation reaction of chlorine with a solution of potassium hydroxide: [2] Cl 2 + 2 KOH → KCl + KOCl + H 2 O. This is the traditional method, first used by Claude Louis Berthollet in 1789. [3] Another production method is electrolysis of potassium chloride solution.
Potassium perchlorate in crystal form. Potassium perchlorate is prepared industrially by treating an aqueous solution of sodium perchlorate with potassium chloride.This single precipitation reaction exploits the low solubility of KClO 4, which is about 1/100 as much as the solubility of NaClO 4 (209.6 g/100 mL at 25 °C).
The ion-permeable ion-exchange membrane at the center of the cell allows only the sodium ions (Na +) to pass to the second chamber where they react with the hydroxide ions to produce caustic soda (NaOH) (B in figure): [1] Na + + OH − → NaOH The overall reaction for the electrolysis of brine is thus: 2NaCl + 2 H 2 O → Cl 2 + H 2 + 2NaOH
The sodium–mercury amalgam flows to the center cell, where it reacts with water to produce sodium hydroxide and regenerate the mercury. Mercury cell electrolysis, also known as the Castner–Kellner process, was the first method used at the end of the nineteenth century to produce chlorine on an industrial scale.