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CH 2 Cl-CH 2 Cl → CH 2 =CHCl + HCl. The resulting HCl can be reused in oxychlorination reaction. Thermally induced dehydrofluorinations are employed in the production of fluoroolefins and hydrofluoroolefins. One example is the preparation of 1,2,3,3,3-pentafluoropropene from 1,1,2,3,3,3-hexafluoropropane: CF 2 HCH(F)CF 3 → CHF=C(F)CF 3 + HF
Such reactions give alkenes in the case of vicinal alkyl dihalides: [2] R 2 C(X)C(X)R 2 + M → R 2 C=CR 2 + MX 2. Most desirable from the perspective of remediation are dehalogenations by hydrogenolysis, i.e. the replacement of a C−X bond by a C−H bond. Such reactions are amenable to catalysis: R−X + H 2 → R−H + HX
Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. [1] This kind of conversion is in fact so common that a comprehensive overview is challenging. This article mainly deals with halogenation using elemental halogens (F 2, Cl 2, Br 2, I 2). Halides are also commonly ...
The traditional name neopentane, coined by William Odling in 1876, [5] was still retained in the 1993 IUPAC recommendations, [6] [7] but is no longer recommended according to the 2013 recommendations. [2] The preferred IUPAC name is the systematic name 2,2-dimethylpropane, but the substituent numbers are superfluous because it is the only ...
Chlorination of benzene under electrophilic aromatic substitution conditions (Cl 2 /FeCl 3 or Cl 2 /AlCl 3) produces chlorobenzene.Since mono chloro-de-hydrogenation deactivates the molecule against further electrophilic reactions, the reaction can be halted at one chlorine atom substitution.
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The R−C(=O)O part is then named as a separate word based on the carboxylic acid name, with the ending changed from "-oic acid" to "-oate" or "-carboxylate" For example, CH 3 CH 2 CH 2 CH 2 COOCH 3 is methyl pentanoate, and (CH 3) 2 CHCH 2 CH 2 COOCH 2 CH 3 is ethyl 4-methylpentanoate.
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