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Mass spectrometry data analysis is specific to the type of experiment producing the data. General subdivisions of data are fundamental to understanding any data. Many mass spectrometers work in either negative ion mode or positive ion mode. It is very important to know whether the observed ions are negatively or positively charged.
Peroxynitrate chemical ionization mass spectrometer at the US National Oceanic and Atmospheric Administration. CI mass spectrometry is a useful tool in structure elucidation of organic compounds. [3] This is possible with CI, because formation of [M+1] + eliminates a stable molecule, which can be used to guess the functional groups present. [3]
Electrospray ionization (ESI) is a technique used in mass spectrometry to produce ions using an electrospray in which a high voltage is applied to a liquid to create an aerosol. It is especially useful in producing ions from macromolecules because it overcomes the propensity of these molecules to fragment when ionized.
In positive ion mode, DART produces predominantly protonated molecules [M+H] + and in negative-ion mode deprotonated molecules [M-H] −. Both negative and positive modes of DART provides relatively simple mass spectra. Depending on the type of analyte, other species may be formed, such as multiple charged adducts. DART is categorized as a soft ...
Atmospheric pressure chemical ionization chamber cross section. Atmospheric pressure chemical ionization (APCI) is an ionization method used in mass spectrometry which utilizes gas-phase ion-molecule reactions at atmospheric pressure (10 5 Pa), [1] [2] commonly coupled with high-performance liquid chromatography (HPLC). [3]
A mass spectrum is a histogram plot of intensity vs. mass-to-charge ratio (m/z) in a chemical sample, [1] usually acquired using an instrument called a mass spectrometer. Not all mass spectra of a given substance are the same; for example, some mass spectrometers break the analyte molecules into fragments ; others observe the intact molecular ...
Sample target for a MALDI mass spectrometer. The type of a mass spectrometer most widely used with MALDI is the time-of-flight mass spectrometer (TOF), mainly due to its large mass range. The TOF measurement procedure is also ideally suited to the MALDI ionization process since the pulsed laser takes individual 'shots' rather than working in ...
It was the first modern mass spectrometer and used positive rays to determine the ratio of the mass to charge of various constituents. [6] In this method, the ion source used an electron beam directed at a solid surface. The anode was made cylindrical in shape using the metal which was to be studied. Subsequently, it was heated by a concentric ...