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Chloroethane, commonly known as ethyl chloride, is a chemical compound with chemical formula CH 3 CH 2 Cl, once widely used in producing tetraethyllead, a gasoline additive. It is a colorless, flammable gas or refrigerated liquid with a faintly sweet odor.
The conditions for Stille's experiments differ significantly from industrial process conditions. Other studies using normal industrial Wacker conditions (except with high chloride and high copper chloride concentrations) also yielded products that inferred nucleophilic attack was an anti-addition reaction. [15]
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
This page was last edited on 19 January 2023, at 06:35 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
In the laboratory it is occasionally used as a source of chlorine, with elimination of ethene and chloride. Via several steps, 1,2-dichloroethane is a precursor to 1,1,1-trichloroethane . Historically, before leaded petrol was phased out, chloroethanes were used as an additive in petrol to prevent lead buildup in engines.
Tetraethyllead was produced from ethyl chloride and a sodium–lead alloy: [11] [12] 4 NaPb + 4 CH 3 CH 2 Cl → Pb(CH 3 CH 2 ) 4 + 4 NaCl + 3 Pb Reductive dechlorination is rarely useful in chemical synthesis, but is a key step in the biodegradation of several organochlorine persistent pollutants .
1,1,1-Trichloroethane is an excellent solvent for many organic compounds and also one of the least toxic of the chlorinated hydrocarbons.It is generally considered non-polar, but owing to the good polarizability of the chlorine atoms, it is a superior solvent for organic compounds that do not dissolve well in hydrocarbons such as hexane.
Oxychlorination is employed in the conversion of ethylene into vinyl chloride. In the first step in this process, ethylene undergoes oxychlorination to give ethylene chloride: CH 2 =CH 2 + 2 HCl + ½ O 2 → ClCH 2 CH 2 Cl + H 2 O. Oxychlorination is of special importance in the making of 1,2-dichloroethane, which is then converted into vinyl ...