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Compared to the first coordination sphere, the second coordination sphere has a less direct influence on the reactivity and chemical properties of the metal complex. Nonetheless the second coordination sphere is relevant to understanding reactions of the metal complex, including the mechanisms of ligand exchange and catalysis.
To define a spherical coordinate system, one must designate an origin point in space, O, and two orthogonal directions: the zenith reference direction and the azimuth reference direction. These choices determine a reference plane that is typically defined as containing the point of origin and the x– and y–axes , either of which may be ...
Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...
In coordination chemistry, the ligand cone angle (θ) is a measure of the steric bulk of a ligand in a transition metal coordination complex. It is defined as the solid angle formed with the metal at the vertex of a cone and the outermost edge of the van der Waals spheres of the ligand atoms at the perimeter of the base of the cone.
The 3-sphere is the boundary of a -ball in four-dimensional space. The -sphere is the boundary of an -ball. Given a Cartesian coordinate system, the unit -sphere of radius can be defined as:
The coordination geometry of an atom is the geometrical pattern defined by the atoms around the central atom. The term is commonly applied in the field of inorganic chemistry, where diverse structures are observed. The coordination geometry depends on the number, not the type, of ligands bonded to the metal centre as well as their locations.
This article uses the standard notation ISO 80000-2, which supersedes ISO 31-11, for spherical coordinates (other sources may reverse the definitions of θ and φ): . The polar angle is denoted by [,]: it is the angle between the z-axis and the radial vector connecting the origin to the point in question.
The first sphere of this row only touches one sphere in the original row, but its location follows suit with the rest of the row. The next row follows this pattern of shifting the x-coordinate by r and the y-coordinate by √ 3. Add rows until reaching the x and y maximum borders of the box.