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In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group (R−O−O−R′). If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article. The O−O bond of peroxides easily breaks, producing free radicals of the form RO • (the dot represents an unpaired ...
Most complexes of η 2-O 2 are generated using hydrogen peroxide, not from O 2. Chromate ([CrO 4)] 2−) can for example be converted to the tetraperoxide [Cr(O 2) 4] 2−. The reaction of hydrogen peroxide with aqueous titanium(IV) gives a brightly colored peroxy complex that is a useful test for titanium as well as hydrogen peroxide. [9]
An oxide is a chemical compound in which one or more oxygen atoms combined with another element, such as H 2 O or CO 2.Based on their acid-base characteristics, oxides can be classified into four categories: acidic oxides, basic oxides, and amphoteric oxides and neutral oxides.
In chemistry, dimerization is the process of joining two identical or similar molecular entities by bonds. The resulting bonds can be either strong or weak. Many symmetrical chemical species are described as dimers, even when the monomer is unknown or highly unstable. [1] The term homodimer is used when the
Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base. H 2 O + H 2 O ⇌ H 3 O + + HO −. The bicarbonate ion, HCO − 3, is amphoteric as it can act as either an acid or a base: As an acid, losing a proton: HCO − 3 + OH − ⇌ CO 2− 3 ...
The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid (H 2 SO 5). In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character. [1]
2 O 3) must be formed by an indirect route. The alkali metals and alkali earth metals all react spontaneously with oxygen when exposed to dry air to form oxides, and form hydroxides in the presence of oxygen and water. As a result, none of these elements is found in nature as a free metal.
In order to study gas phase interstellar chemistry, it is convenient to distinguish two types of interstellar clouds: diffuse clouds, with T=30-100 K, and n=10–1000 cm −3, and dense clouds with T=10-30K and density n= 10 4-10 3 cm −3. Ion chemical routes in both dense and diffuse clouds have been established for some works (Hartquist 1990).