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Germanium tetrafluoride is a noncombustible, strongly fuming gas with a garlic-like odor. It reacts with water to form hydrofluoric acid and germanium dioxide.
Its structure was determined by both NMR spectroscopy and X-ray crystallography in 1963. [6] [7] The structure is square planar, as has been confirmed by neutron diffraction studies. [8] According to VSEPR theory, in addition to four fluoride ligands, the xenon center has two lone pairs of electrons. These lone pairs are mutually trans.
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Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
Germanium difluoride forms orthorhombic crystals with a space group P2 1 2 1 2 1 (No. 19), Pearson symbol oP12, and lattice constants a = 0.4682 nm, b = 0.5178 nm, c = 0.8312 nm, Z = 4 (four structure units per unit cell). Its crystal structure is characterized by strong polymeric chains composed by GeF 3 pyramids.
[7] [8] While Lewis supported the viewpoint of expanded octet, invoking s-p-d hybridized orbitals and maintaining 2c–2e bonds between neighboring atoms, Langmuir instead opted for maintaining the octet rule, invoking an ionic basis for bonding in hypervalent compounds (see Hypervalent molecule, valence bond theory diagrams for PF 5 and SF 6). [9]
Its crystal structure may allow it to replace silicon in silicate minerals. [13] The XeOO + cation has been identified by infrared spectroscopy in solid argon. [14] Xenon does not react with oxygen directly; the trioxide is formed by the hydrolysis of XeF 6: [15] XeF 6 + 3 H 2 O → XeO 3 + 6 HF. XeO
Structure of chlorine trifluoride, an example of a compound with T-shaped coordination geometry. In chemistry, T-shaped molecular geometry describes the structures of some molecules where a central atom has three ligands. Ordinarily, three-coordinated compounds adopt trigonal planar or pyramidal geometries.