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SO 2 + NaOH → NaHSO 3 SO 2 + NaHCO 3 → NaHSO 3 + CO 2. Attempts to crystallize the product yield sodium metabisulfite (also called sodium disulfite), Na 2 S 2 O 5. [6] Upon dissolution of the metabisulfite in water, bisulfite is regenerated: Na 2 S 2 O 5 + H 2 O → 2 Na + + 2 HSO 3 −. Sodium bisulfite is formed during the Wellman-Lord ...
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The roasting of sulfide ores such as pyrite, sphalerite, and cinnabar (mercury sulfide) also releases SO 2: [19] 4 FeS 2 + 11 O 2 → 2 Fe 2 O 3 + 8 SO 2 2 ZnS + 3 O 2 → 2 ZnO + 2 SO 2 HgS + O 2 → Hg + SO 2 4 FeS + 7 O 2 → 2 Fe 2 O 3 + 4 SO 2. A combination of these reactions is responsible for the largest source of sulfur dioxide ...
Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO 2, SO 3, S 7 O 2, S 6 O 2, S 2 O 2, etc. Sulfur oxide (SO x) refers to one or more of the following: Lower sulfur oxides (S n O, S 7 O 2 and S 6 O 2) Sulfur monoxide (SO) and its dimer, Disulfur dioxide (S 2 O 2) Sulfur dioxide (SO 2) Sulfur trioxide (SO 3)
When conducted in warm water, Na 2 SO 3 initially precipitates as a white solid. With more SO 2, the solid dissolves to give the disulfite, which crystallizes upon cooling. [2] SO 2 + 2 NaOH → Na 2 SO 3 + H 2 O. Sodium sulfite is made industrially by treating sulfur dioxide with a solution of sodium carbonate. [3] The overall reaction is:
Aluminum amalgam (Al/Hg) may be used for the chemoselective reduction of α-sulfonylated carbonyl groups. Carboxylic acid derivatives, acetals, thioacetals, amines, alcohols, and isolated double bonds are all inert to Al/Hg. Selective desulfonylation may be carried out on β-hydroxy sulfones without reductive elimination.
Sulfurous acid is commonly known to not exist in its free state, and due to this, it is stated in textbooks that it cannot be isolated in the water-free form. [4] However, the molecule has been detected in the gas phase in 1988 by the dissociative ionization of diethyl sulfite. [5]
Sulfonyl group (R-SO 2-R), a functional group found primarily in sulfones, or a substituent; SO(2), special orthogonal group of degree 2 in mathematics; Oxygen saturation (SO 2), the concentration of oxygen dissolved in a medium; S2 (star) or S0–2, a star near the central black hole at the center of the Milky Way; 2015 SO 2 or 2015 SO2, an ...