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The Koch reaction is an organic reaction for the synthesis of tertiary carboxylic acids from alcohols or alkenes and carbon monoxide. Some commonly industrially produced Koch acids include pivalic acid , 2,2-dimethylbutyric acid and 2,2-dimethylpentanoic acid. [ 1 ]
A 3–5% aqueous solution of KOH is applied to the flesh of a mushroom and the researcher notes whether or not the color of the flesh changes. Certain species of gilled mushrooms, boletes, polypores, and lichens [25] are identifiable based on this color-change reaction. [26]
For example, when 2-iodobutane is treated with alcoholic potassium hydroxide (KOH), but-2-ene is the major product and but-1-ene is the minor product. [ 1 ] More generally, Zaytsev's rule predicts that in an elimination reaction the most substituted product will be the most stable, and therefore the most favored.
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
A 3–10% solution of potassium hydroxide (KOH) gives a color change in some species of mushrooms: In Agaricus, some species such as A. xanthodermus turn yellow with KOH, many have no reaction, and A. subrutilescens turns green. Distinctive change occurs for some species of Cortinarius and Boletes
The resulting HCl can be reused in oxychlorination reaction. Thermally induced dehydrofluorinations are employed in the production of fluoroolefins and hydrofluoroolefins . One example is the preparation of 1,2,3,3,3-pentafluoropropene from 1,1,2,3,3,3-hexafluoropropane:
2 C 6 H 5 CHO + KOH → C 6 H 5 CH 2 OH + C 6 H 5 COOK. The process is a redox reaction involving transfer of a hydride from one substrate molecule to the other: one aldehyde is oxidized to form the acid, the other is reduced to form the alcohol. [3]
Potassium persulfate can be prepared by electrolysis of a cold solution potassium bisulfate in sulfuric acid at a high current density. [1] [4]2 KHSO 4 → K 2 S 2 O 8 + H 2. It can also be prepared by adding potassium bisulfate (KHSO 4) to a solution of the more soluble salt ammonium peroxydisulfate (NH 4) 2 S 2 O 8.