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where N v is the vacancy concentration, Q v is the energy required for vacancy formation, k B is the Boltzmann constant, T is the absolute temperature, and N is the concentration of atomic sites i.e. = where ρ is density, N A the Avogadro constant, and M the molar mass. It is the simplest point defect.
For example, the defect may result in an ion on its own ion site or a vacancy on the cation site. To complete the reactions, the proper number of each ion must be present (mass balance), an equal number of sites must exist (site balance), and the sums of the charges of the reactants and products must also be equal (charge balance).
Simplified atomic structure of the NV center. The nitrogen-vacancy center (N-V center or NV center) is one of numerous photoluminescent point defects in diamond.Its most explored and useful properties include its spin-dependent photoluminescence (which enables measurement of the electronic spin state using optically detected magnetic resonance), and its relatively long (millisecond) spin ...
Electron microscopy of antisites (a, Mo substitutes for S) and vacancies (b, missing S atoms) in a monolayer of molybdenum disulfide.Scale bar: 1 nm. [1]A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in crystalline solids.
F-center in an NaCl crystal. An F-center or color center or Farbe center (from the original German Farbzentrum, where Farbe means color and zentrum means center) is a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more unpaired electrons.
A Schottky defect is an excitation of the site occupations in a crystal lattice leading to point defects named after Walter H. Schottky.In ionic crystals, this defect forms when oppositely charged ions leave their lattice sites and become incorporated for instance at the surface, creating oppositely charged vacancies.
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In crystallography, a Frenkel defect is a type of point defect in crystalline solids, named after its discoverer Yakov Frenkel. [1] The defect forms when an atom or smaller ion (usually cation) leaves its place in the structure, creating a vacancy and becomes an interstitial by lodging in a nearby location. [2]