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Abbot's Kitchen chemistry laboratory in Oxford Detail of a wood engraving by W. E. Hodgkin of 1855 showing the Abbot's Kitchen. The Abbot's Kitchen in Oxford, England, is an early chemistry laboratory based on the Abbot's Kitchen at Glastonbury Abbey, a mediaeval 14th-century octagonal building that served as the kitchen at the abbey.
In chemistry and biochemistry, the Henderson–Hasselbalch equation = + ([] []) relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, K a, of acid and the ratio of the concentrations, [] [] of the acid and its conjugate base in an equilibrium.
The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...
pK a1 = 3.13, pK a2 = 4.76, pK a3 = 6.40. A weak acid may be defined as an acid with pK a greater than about −2. An acid with pK a = −2 would be 99 % dissociated at pH 0, that is, in a 1 M HCl solution. Any acid with a pK a less than about −2 is said to be a strong acid. Strong acids are said to be fully dissociated.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
Ab initio quantum chemistry methods are a class of computational chemistry techniques based on quantum chemistry that aim to solve the electronic Schrödinger equation. [1] Ab initio means "from first principles" or "from the beginning", meaning using only physical constants [ 2 ] and the positions and number of electrons in the system as input.
Such a calculation in the Gaussian and Spartan programs also give the MP2 and MP4 energies which are also used. The effect of polarization functions is assessed using an MP4 calculation with the 6-311G(2df,p) basis set. The effect of diffuse functions is assessed using an MP4 calculation with the 6-311+G(d, p) basis set.
The batching matrix B indicates the relation of the molarity in the batch (columns) and in the glass (rows). For example, the batch component SiO 2 adds 1 mol SiO 2 to the glass, therefore, the intersection of the first column and row shows "1". Trona adds 1.5 mol Na 2 O to the glass; albite adds 6 mol SiO 2, 1 mol Na 2 O, and 1 mol Al 2 O 3 ...