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Typical crack pattern of the alkali-silica reaction (ASR). The gel exudations through the concrete cracks have a characteristic yellow color and a high pH. The fatty aspect of the exudations imbibing the concrete porosity along the cracks is also a distinctive feature of ASR. The alkali-silica reaction as a chemical cycle process
Oxidation of pyrite in clay formations in contact with concrete – this produces sulfuric acid which reacts with concrete. Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S).
The curing of concrete when it continues to harden after its initial setting and progressively develops its mechanical strength is a critical phase to avoid unwanted cracks in concrete. Depending on the temperature (summer or winter conditions) and thus on the cement hydration kinetics controlling the setting and hardening rate of concrete ...
Michigan Concrete Association recommends a regular salt like Morton table salt instead of an ice melter because it’s 100 percent sodium chloride (NaCl). This, however, is recommended for ...
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
Aluminium sulfate is a salt with the formula Al 2 (SO 4) 3. It is soluble in water and is mainly used as a coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water [ 3 ] [ 4 ] and wastewater treatment plants , and also in paper manufacturing.
When a reinforced concrete member is put in tension, after cracking, the member elongates by widening of cracks and by formation of new cracks. Figure 1 Formation of internal cracks. Ignoring the small elastic strain in the concrete between the cracks, we can relate the crack width to the strain of the member by:
The cement is a hydraulic binder whose hydration requires water. It can perfectly set under water. Water is essential to its hardening and water losses must be avoided at the young age to avoid the development of cracks. Young concrete is protected against desiccation (evaporation of unreacted water). Traditional methods for preventing ...