Search results
Results From The WOW.Com Content Network
It reduces solutions of noble metal cations to the metals. When phosphorous acid is treated with a cold solution of mercuric chloride, a white precipitate of mercurous chloride forms: H 3 PO 3 + 2 HgCl 2 + H 2 O → Hg 2 Cl 2 + H 3 PO 4 + 2 HCl. Mercurous chloride is reduced further by phosphorous acid to mercury on heating or on standing:
Symmetrical 1,3,5-triazines are prepared by trimerization of certain nitriles such as cyanogen chloride or cyanamide.Benzoguanamine (with one phenyl and 2 amino substituents) is synthesised from benzonitrile and dicyandiamide. [2]
The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question. Substitutional solid solutions, in accordance with the Hume-Rothery rules, may form if the solute and solvent have: Similar atomic radii (15% or less difference)
This translates into the smaller force constant of the bond (2.8 N/cm vs. 11.4 N/cm for 3 O 2) and the lower frequency of the molecular vibration (770 cm −1 vs. 1555 cm −1 for 3 O 2). [ 2 ] The peroxide ion can be compared with superoxide O − 2 , which is a radical, and dioxygen, a diradical.
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula . For example, a solution of table salt , also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq) .
An illustrative example is the effect of catalysts to speed the decomposition of hydrogen peroxide into water and oxygen: . 2 H 2 O 2 → 2 H 2 O + O 2. This reaction proceeds because the reaction products are more stable than the starting compound, but this decomposition is so slow that hydrogen peroxide solutions are commercially available.
In modern chemistry, a chemical formula is a way of expressing information about the proportions of atoms that constitute a particular chemical compound, using a single line of chemical element symbols, numbers, and sometimes other symbols, such as parentheses, brackets, and plus (+) and minus (−) signs. [9]
In chemistry, pyrophosphates are phosphorus oxyanions that contain two phosphorus atoms in a P−O−P linkage. A number of pyrophosphate salts exist, such as disodium pyrophosphate (Na 2 H 2 P 2 O 7) and tetrasodium pyrophosphate (Na 4 P 2 O 7), among others. Often pyrophosphates are called diphosphates.