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Oxygen difluoride. A common preparative method involves fluorination of sodium hydroxide: 2 F 2 + 2 NaOH → OF 2 + 2 NaF + H 2 O. OF 2 is a colorless gas at room temperature and a yellow liquid below 128 K. Oxygen difluoride has an irritating odor and is poisonous. [3] It reacts quantitatively with aqueous haloacids to give free halogens:
It decomposes in water to form oxygen gas, oxygen difluoride, hydrofluoric acid, and nitric acid. [1] In fluorine nitrate, the oxygen atom bridging nitrogen and fluorine is in a rare oxidation state of 0 due to its electronegativity being lower than that of fluorine but higher than that of nitrogen.
Oxygen difluoride was first reported in 1929; it was obtained by the electrolysis of molten potassium fluoride and hydrofluoric acid containing small quantities of water. [7] [8] The modern preparation entails the reaction of fluorine with a dilute aqueous solution of sodium hydroxide, with sodium fluoride as a side-product:
Compounds containing oxygen in other oxidation states are very uncommon: − 1 ⁄ 2 (superoxides), − 1 ⁄ 3 , 0 (elemental, hypofluorous acid), + 1 ⁄ 2 , +1 (dioxygen difluoride), and +2 (oxygen difluoride). Oxygen is reactive and will form oxides with all other elements except the noble gases helium, neon, argon and krypton. [1]
The bond energy is significantly weaker than those of Cl 2 or Br 2 molecules and similar to the easily cleaved oxygen–oxygen bonds of peroxides or nitrogen–nitrogen bonds of hydrazines. [8] The covalent radius of fluorine of about 71 picometers found in F 2 molecules is significantly larger than that in other compounds because of this weak ...
Nitrogen difluoride is formed during the function of a xenon monofluoride excimer laser. Nitrogen trifluoride is the halide carrier gas, which releases fluoride ions when impacted by electrons: [1] NF 3 + e − → NF 2 + F −. The free fluoride ion goes on to react with xenon cations. [1] Nitrogen difluoride can be consumed further to yield ...
However, the hydrogen bonding in NH 3 is weaker than that in H 2 O due to the lower electronegativity of nitrogen compared to oxygen and the presence of only one lone pair in NH 3 rather than two in H 2 O. It is a weak base in aqueous solution (pK b 4.74); its conjugate acid is ammonium, NH + 4.
It is also the only hypohalous acid that can be isolated as a solid. HOF is an intermediate in the oxidation of water by fluorine, which produces hydrogen fluoride, oxygen difluoride, hydrogen peroxide, ozone and oxygen. HOF is explosive at room temperature, forming HF and O 2: [1] 2 HOF → 2 HF + O 2. This reaction is catalyzed by water. [2]