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Silver, although it is the least resistive metal known, has a high density and performs similarly to copper by this measure, but is much more expensive. Calcium and the alkali metals have the best resistivity-density products, but are rarely used for conductors due to their high reactivity with water and oxygen (and lack of physical strength).
An electrical insulator is a material in which electric current does not flow freely. The atoms of the insulator have tightly bound electrons which cannot readily move. Other materials—semiconductors and conductors—conduct electric current more easily.
Liquids made of compounds with only covalent bonds cannot conduct electricity. Certain organic ionic liquids , by contrast, can conduct an electric current. While pure water is not an electrical conductor, even a small portion of ionic impurities, such as salt , can rapidly transform it into a conductor.
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.
Metals are insoluble in water or organic solvents, unless they undergo a reaction with them. Typically, this is an oxidation reaction that robs the metal atoms of their itinerant electrons, destroying the metallic bonding. However metals are often readily soluble in each other while retaining the metallic character of their bonding.
Wood generally conducts better along the grain than across it. Other examples of materials where the thermal conductivity varies with direction are metals that have undergone heavy cold pressing, laminated materials, cables, the materials used for the Space Shuttle thermal protection system, and fiber-reinforced composite structures. [27]
A metal conducts electricity at a temperature of absolute zero, [5] which is a consequence of delocalized states at the Fermi energy. [1] [2] Many elements and compounds become metallic under high pressures, for example, iodine gradually becomes a metal at a pressure of between 40 and 170 thousand times atmospheric pressure.
Almost any conductive wire can be used for heating, but most metals conduct electricity with great efficiency, requiring them to be formed into very thin and delicate wires to create enough resistance to generate heat. When heated in air, most metals then oxidize quickly, become brittle and break.