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Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. It is a component of coal tar . Anthracene is used in the production of the red dye alizarin and other dyes, as a Scintillator to detect high energy particles, as production of pharmaceutical drugs.
An aromatic π-sextet can be represented by a circle, as in the case of the anthracene molecule (below). Clar's rule states that for a benzenoid polycyclic aromatic hydrocarbon (i.e. one with only hexagonal rings), the resonance structure with the largest number of disjoint aromatic π-sextets is the most important to characterize its chemical ...
A Polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings.Most are produced by the incomplete combustion of organic matter— by engine exhaust fumes, tobacco, incinerators, in roasted meats and cereals, [1] or when biomass burns at lower temperatures as in forest fires.
Diboraanthracene is a class of boron heterocyclic compounds in which two boron atoms substitute two carbon atoms in anthracene (C₁₄H₁₀), one of the typical polycyclic aromatic hydrocarbons (PAHs). The most well-studied diboraanthracene is 9,10-disubstituted-9,10-diboraanthracene (DBA) and its doubly reduced dianion (DBA²⁻).
It is also possible to synthesise heterocyclic compounds via the Elbs reaction. In 1956 an Elbs reaction of a thiophene derivative was published. The expected linear product was not obtained due to a change in reaction mechanism after formation of the first intermediate which caused multiple free radical reaction steps. [6] Heterocyclic Elbs ...
The reaction of anthracene with N-methylformanilide, also using phosphorus oxychloride, gives 9-anthracenecarboxaldehyde: N -Methylformanilide and anthracene and phosphorus oxychloride In general, the electron-rich arene ( 3 ) must be much more active than benzene for the reaction to proceed; phenols or anilines are good substrates.
Anthraquinone, also called anthracenedione or dioxoanthracene, is an aromatic organic compound with formula C 14 H 8 O 2. Several isomers exist but these terms usually refer to 9,10-anthraquinone (IUPAC: 9,10-dioxoanthracene) wherein the keto groups are located on the central ring. It is used as a digester additive to wood pulp for papermaking.
The name "anthraquinone" was first used by German chemists Carl Graebe and Carl Theodore Liebermann in a 1868 publication describing the chemical synthesis of the red dye alizarin from anthracene, a component of coal tar. This discovery led to the industrial production of alizarin and the impetus for further research on anthraquinone chemistry. [1]