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Moreover, chlorophyll b can be directly reduced (via 7 1-hydroxychlorophyll a) back to chlorophyll a, completing the cycle. [ 42 ] [ 43 ] In later stages of senescence, chlorophyllides are converted to a group of colourless tetrapyrroles known as nonfluorescent chlorophyll catabolites (NCC's) with the general structure:
The phytol ester of chlorophyll a (R in the diagram) is a long hydrophobic tail which anchors the molecule to other hydrophobic proteins in the thylakoid membrane of the chloroplast. [5] Once detached from the porphyrin ring, phytol becomes the precursor of two biomarkers , pristane and phytane , which are important in the study of geochemistry ...
The action spectra of chlorophyll molecules are slightly modified in vivo depending on specific pigment–protein interactions. The process of photosynthesis provides the main input of free energy into the biosphere, and is one of four main ways in which radiation is important for plant life.
The pair of chlorophyll molecules at the reaction center are often referred to as P680. [1] When the photon has been absorbed, the resulting high-energy electron is transferred to a nearby pheophytin molecule. This is above and to the right of the pair on the diagram and is coloured grey.
The antenna pigments are predominantly chlorophyll b, xanthophylls, and carotenes. Chlorophyll a is known as the core pigment. Their absorption spectra are non-overlapping and broaden the range of light that can be absorbed in photosynthesis. The carotenoids have another role as an antioxidant to prevent photo-oxidative damage of chlorophyll ...
At the center of the reaction center is a special pair of chlorophyll molecules. Each PSII has about 8 LHCII. These contain about 14 chlorophyll a and chlorophyll b molecules, as well as about four carotenoids. In the reaction center of PSII of plants and cyanobacteria, the light energy is used to split water into oxygen, protons, and electrons.
Top: Absorption spectra for chlorophyll-A, chlorophyll-B, and carotenoids extracted in a solution. Bottom: PAR action spectrum (oxygen evolution per incident photon) of an isolated chloroplast. Chlorophyll , the most abundant plant pigment, is most efficient in capturing red and blue light.
P680 + is the strongest biological oxidizing agent known, with an estimated redox potential of ~1.3 V. [3] This makes it possible to oxidize water during oxygenic photosynthesis. P680 + recovers its lost electron by oxidizing water via the oxygen-evolving complex , which regenerates P680.