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Magnesium chloride is an inorganic compound with the formula Mg Cl 2. ... The octahydrate and the dodecahydrate can be crystallized from water below 298K.
Magnesium chloride is an ionic compound, which can be electrolysed in a molten state to form magnesium and chlorine gas. The properties of magnesium bromide and magnesium iodide are similar. [citation needed] HMgX (X=Cl,Br,I) can be obtained by reacting the corresponding magnesium halide with magnesium hydride. [3]
The second water in the formula unit is hydrogen-bonded to the chloride and to the coordinated water molecule. Water of crystallization is stabilized by electrostatic attractions, consequently hydrates are common for salts that contain +2 and +3 cations as well as −2 anions.
The magnesium chloride can be obtained using the Dow process, a process that mixes sea water and dolomite in a flocculator or by dehydration of magnesium chloride brines. The electrolytic cells are partially submerged in a molten salt electrolyte to which the produced magnesium chloride is added in concentrations between 6–18%. [44]
Magnesium hydroxychloride [1] is the traditional term for several chemical compounds of magnesium, chlorine, oxygen, and hydrogen whose general formula xMgO·yMgCl 2 ·zH 2 O, for various values of x, y, and z; or, equivalently, Mg x+y (OH) 2x Cl 2y (H 2 O) z−x.
Vapor-deposited magnesium crystals from the Pidgeon process. The Pidgeon process is a practical method for smelting magnesium.The most common method involves the raw material, dolomite being fed into an externally heated reduction tank and then thermally reduced to metallic magnesium using 75% ferrosilicon as a reducing agent in a vacuum. [1]
Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposition directly from a gas. Attributes of the resulting crystal depend largely on factors such as temperature, air pressure, cooling rate, and in the case of liquid crystals, time of fluid evaporation. Crystallization occurs in two major steps.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).