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O h, *432, [4,3], or m3m of order 48 – achiral octahedral symmetry or full octahedral symmetry. This group has the same rotation axes as O, but with mirror planes, comprising both the mirror planes of T d and T h. This group is isomorphic to S 4.C 2, and is the full symmetry group of the cube and octahedron. It is the hyperoctahedral group ...
(To some extent rotation influences the geometry via Coriolis forces and centrifugal distortion, but this is negligible for the present discussion.) In addition to translation and rotation, a third type of motion is molecular vibration , which corresponds to internal motions of the atoms such as bond stretching and bond angle variation.
The following are the main features [4] of the latest version of OctaDist: Structural distortion analysis Determination of regular and irregular distorted octahedral molecular geometry; Octahedral distortion parameters [5] [6] [7] Volume of the octahedron; Tilting distortion parameter for perovskite complex [8] Molecular graphics. 3D modelling ...
A perfect octahedron belongs to the point group O h. Examples of octahedral compounds are sulfur hexafluoride SF 6 and molybdenum hexacarbonyl Mo(CO) 6 . The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves.
The unit cell is defined as the smallest repeating unit having the full symmetry of the crystal structure. [2] The geometry of the unit cell is defined as a parallelepiped , providing six lattice parameters taken as the lengths of the cell edges ( a , b , c ) and the angles between them (α, β, γ).
The rhombic dodecahedron can be viewed as the convex hull of the union of the vertices of a cube and an octahedron where the edges intersect perpendicularly. The six vertices where four rhombi meet correspond to the vertices of the octahedron, while the eight vertices where three rhombi meet correspond to the vertices of the cube.
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A regular octahedron is an octahedron that is a regular polyhedron. All the faces of a regular octahedron are equilateral triangles of the same size, and exactly four triangles meet at each vertex. A regular octahedron is convex, meaning that for any two points within it, the line segment connecting them lies entirely within it.